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calcium nitride : ウィキペディア英語版
calcium nitride

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Calcium nitride is the inorganic compound with the chemical formula Ca3N2. It exists in various forms (isomorphs), α-calcium nitride being more commonly encountered.
==Structure==
α-Calcium nitride adopts an anti-bixbyite structure, similar to Mn2O3, except that the positions of the ions are reversed: calcium (Ca2+) take the oxide (O2−) positions and nitride ions (N3−) the manganese (Mn3+). In this structure, Ca2+ occupies tetrahedral sites, and the nitride centres occupy two different types of octahedral sites.〔Wells, A.F. (1984) Structural Inorganic Chemistry, Oxford: Clarendon Press. ISBN 0-19-855370-6.〕

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